AFAIK, unless you have a government issued "indigenous person" id, you pay the going area price for whatever you buy. Only the aboriginals get the cheaper price/rate.
That may have changed, but that's how it worked a few years ago. Used to live and drive near the Brantford 6 Nations area when we lived nearer to it, and pulled in once, only to find that we didn't qualify for the much lower price displayed on their price signage.
Maybe some of the on reserve stations (Mohawks?) don't care any more, and sell it to everyone now?
Got a Costco card? There must be a few along your route, and they're probably the cheapest, just off the 401.
Official government blah blah
https://www.fin.gov.on.ca/en/bulletins/gt/3_2011.html