First: If you have 100 PSI at the park pedestal DO NOT HOOK UP Your RV is likely rated for no more than 50 PSI.. Instead use a Good Pressure Regulator, I recommend any of the following
Watts 1/2 inch or larger with hose adapters
Zurin 1/2 inch or larger with hose adapters
and though I've not PERSONALLY tested: Valterra adjustable
NOTE: My Watts and Zurin are both 3/4 inch
When new.. I set these to 50 PSI and open a Shower.. The needle does not move on the pressure gauge.. as they age,, it starts to move, but you can rebuild them. (I need to get a Watts Kit).
Now to your question:
Does the pressure increase due to the sun.. the answer is both yes and no.. YEs but by a very tiny fraction of a PSI you will never notice.... The park's pressure tank or the city pressure tank, will absorb any increase.
NOTE: one park I visit is 120 PSI by measurement... They blow hoses apart there often.. That's why I have the ZURIN, it holds at a solid 50 PSI and I mean SOLID.