A battery has 6 cells connected together in series with only two external posts.
Similarly, Think of two batteries connected together in parallel as a single battery or box. One wire coming out to ground, another wire to positive. A switch on either wire would isolate the whole double battery. One of the wires will come directly from a battery post so the aforementioned disconnect could be attached to that post.
However, that post will have a second wire on it, going to the same polarity post on the other battery. Could be tricky getting the wire and the switch on the same post.