18W is good for ~250 or 300 AH battery bank in storage. So - yes, 2*6V batts. It probably doesn't have any current regulator, only a night-time diode. For a car battery you can go with a smaller 5W-10W charger.
There are few issues with these 1W-20W chargers:
1) Not weatherproof, can short or corrode in rain.
2) Not temperature-proof, plastic casing can melt in a hot sun if left under windshield.
3) Poor quality crocodile clamps, they corrode in a matter of weeks even when there is no rain - because of chemical reaction on battery contacts.