Mendy must be from Nova Scotia, calling everyone, "Dear." :)
The general rule for Voc limit is to use the voltage coefficient on the Voc rating (for 25C) and get the figure for the coldest ambient you expect to be camping in, so 45 Voc is still borderline for a pair of 12s at 22 Voc each in really cold temps.
That rule must be just for the first minute after switching on/hooking up because the panel warms up fast in the sun no matter what the ambient is. I think 45 would be just enough to get away with it in many scenarios where 42 would not be though.
I would wait till the panels did warm up in the sun and then hook in the Eco-W to give a little more margin.
Good to know, thanks!