First off.......
Your propane 'cylinder' is not old, obsolete etc.
OPD service valves have been factory installed since 1998
Your 13 yr old cylinder NEEDS to be recertified (required 12 yrs after date of mfg stamped oon collar)
Visual recert good for 5 yrs. then again every 5 yrs.
Secondly......
OPD is an 'overfilling protective device'.....stops the liquid filling at 80% liquid level
OPD does NOT stop vapor flow out of cylinder.
(Full cylinder --- float at upper limit stopping liquid but vapor still flows out. Even if float stayed at upper limit)
Thirdly....
OPD has a 'spring loaded shutoff valve' that can interfere with filling and WILL stop vapor flow out of cylinder
IF the propane vendors fill adapter does not OPEN the shutoff valve OR the pigtail hose is not screwed on tight enough then propane will not flow out.
There is a 'stud' inside the ACME Nut on pigtail hose that pushes the spring loaded shutoff valve open.
Vendors fill adapter must do the same
Also ACME Nut has a 'thermal bushing'(melts in fire--internals of ACME Nut slips back and spring loaded shutoff valve in OPD closes)
If bushing is old, weaken, cracked etc 'stud' could have problems pushing open the OPD shutoff valve.
Especially if you have the OLD style (first edition) bushing
Fourthly.....
Also quickly opening the OPD can trip the 'excess flow device' INSIDE the ACME Nut.
Close OPD wait 30 seconds and then SLOWLY open OPD
Fifthly.......
Shooting a full propane cylinder with a firearm will cause a Hole in cylinder and allow propane to spew out. But it will NOT cause it to explode or a big flash etc.
Must have a source of 'ignition' to light off the propane VAPOR
MythBusters episode 95. Look it up.
OPD---triangular handle, relief valve, liquid level 'bleeder' valve and connection (shutoff inside)

ACME Nut 'stud' that opens OPD spring loaded shutoff vlave

ACME Nut 'excess flow device' ---spring loaded ball bearing

ACME Nut thermal bushing (First Edition)

ACME Nut thermal bushing (Current Version)

IF anything is stopping the flow of propane vapor it would be either the 'ACME Nut excess flow device' OR the OPD spring loaded shutoff valve