A chemical odorant, ethyl mercaptan, is induced into liquid propane during the distilling process to insure that if a leak occurs, the user would indeed be made aware of it.
Liquid propane is inherently odorless and colorless and as potent as LP is, the odorant is added as a safety feature. Since the mercaptan is heavier than the liquid propane, it eventually settles to the bottom of the tank.
When a tank is near empty, the percentage of mercaptan relative to the remainder of the liquid fuel is far greater than normal. When LP is utilized in RV appliances as a vapor during this low level situation, some of the odorant can seep into the appliances and become evident to the user.
In furnaces, this phenomenon is usually kept to a minimum since the furnace is a completely sealed system and uses outside air to mix with the LP for combustion.