WVvan, Nice wiring diagram!
The only thing I'd recommend is a higher amperage charger.
I'm running 2 12 volts, but when I do need to plug in and use a charger, my 25 amp charger takes too long, because it only puts out 25 amps in the beginning.
If a 15 amp charger tapered the amps at the same rate, it will take forever to bring your twin 6 volts back up past 85%.
I used to have 3 12 volts and would use the 130 watt solar in the coastal desert to charge all 3. The monitor would say 100% daily, but the day after I'd hit them with 25 amps they'd hold more voltage overnight.
Now I have only the 2 remaining in parallel I can tell that 230 A/his a better match with my 130 watt panel.
I've found I don't need 345 a/h of batteries, and when I can afford it, I'm getting 2 31DC36 Crown 12 volts @ 140 A/h a piece and only charging one at a time with the solar or alternator and solar combo, and keeping the other one isolated, and switching the load/charge battery every other day or 2 via my boat battery 1,2,Both,Off switch.
I have not used a "starting battery" in years, the Everstart dual purpose quasi deep cycles have enough CCA to crank my V8. In fact my engine compartment battery tray has been empty for well over a year now. My house batteries are #2, and I just leave the Perko switch to #2.
Where are you putting the 6 volts?
Is that what the welder is doing?