in high power installs (Say house 120 volt back up) higher voltages = smaller wires but in an RV the wires are not that long... There may be other issues too but I'd stick with 12 volt cause that's what you eat.
Arguing against other configurations: IN order to feed your 12 volt stuff including Control power for Fridge, Water heater and AC as well as lights (You can buy other voltages) fans (Theroatically you can get other voltages) and the Furnace (12 volt) and water pump (12 volt) you will need to "Convert" the higher voltage down.. There are several "Conversion" methods which range from wasteful to WASTEFUL!!!! of energy... None are 100%.. so your most effieicent install will be 12 volt all the way.. Well. 13.6-14.2 but but we still call it 12.