sjturbo,
I believe what they are saying is check the V readings while charging.
Because of V drop across the cables, the charger could be putting out 15v, but the batteries may read only 14.85v, or whatever. But the battery V will come up, eventually. So you need to take each reading at the charger's outputs, as well as at the battery terminals.
Another thing to watch for is equal V readings across individual batteries, during charging, as well as while resting. So, for example, if a pair of 6v batts in series are getting 14.8v, at the battery terminals, then both 6v should read 7.4v, not 7.3 and 7.5. Likewise, if they are resting (leveled out) at 12.7v, they should both be equal at 6.35v.
As for 'waiting' to take V readings, that is for getting the resting V. And after a good top charge, that could take several days of resting, with no loads, for the "surface charge" to self discharge. For example, yesterday evening, I brought my two 215Ah banks to 2.25a/14.89v and 2.4a/14.88v . 12 hours later, they still read 12.93v and 12.91v, but they usually settle at about 12.78v.
The important thing to measure is SG. After several charge cycles, each followed by a good top up, the SG will likely improve. This will then be your "baseline" SG, as these guys have taught me. You can take SG readings after each 15 minute interval, but there may be some lag. Take readings throughout, and then an hour or two after, and compare.
I generally wait until (at least) the next day to check SG after an actual EQ, but that can't happen if the batts need to be put back into to service right away.