Sooting is due to lack of AIR....fuel rich flame
Clean burner tube....remove and swab with small bottle brush
Clean orifice...remove/soak in alcohol and then blow on it (LOW air pressure)
Swab combustion/exhaust chamber to clear of soot and/or debris ,,,,,push a wire thru combustion inlet---out the exhaust. Tie rag to the wire and pull back thru
If you have an Atwood you can adjust air inlet by opening the air shutter a bit more.
But typically sooting is due to 'stuff' obstructing air/fuel mixing...a spider web can cause enough of an obstruction to disrupt proper air/fuel mixing