The process for the propane refrigerator has been around for many years. I can remember one from back when I was a kid in the 40's... It is truly amazing how you can put fire or heat in one end and get cooling out of the other end.
Reading up on-line it says the refrigerant in LP gas/ electric refrigerators is ammonia- the oldest refrigerant used.
In an RV refrigerator, the heat can by generated by an LP gas flame or an electric heating element- the heating element can be 120 volt AC, or 12 volt DC.
With all of this in mind there really shouldn't be any difference whether you use a gas flame or electric heating element as long as the ammonia gets heated up properly. The only difference maybe might be dirty flue or poor connections etc...
I would think keeping the fridge in the a cool environment as best you can would be the best of all worlds. Parking where the high sun always hits the outside wall of the fridge probably not a good idea.
Roy Ken