100 amp hours @ 12 volts -- 24 volts 120 volts.
Amp hours is a shortcut. It is an assumption figure. You know how much energy you require. To say pump 100 gallons of water. Is the pump going to deliver the same gallonage at 13.6 volts as it does at 12.1 volts?
If you feed a 50 watt array of regulated LED lamps at 14.4 volts instead of 12.2 volts will the same amount of energy be extracted out of a storage battery? The lamps operate from 10 to 30 volts.
Watt hours provides a true quantity of energy. Your home meter displays kWh for a reason.
How you can benefit (or not) by utilizing the wattage measure is the question.