Unrelated. The pressure relief valve is designed to open should a set pressure (temperature) be reached. A lot of folks use them as an air port to drain the heater or muck with them to recreate the interior air reserve. I never touch them as I've experienced failures by opening them. Sometimes, an O-ring will become unseated or tear when the valve is opened. Sometimes, accumulated mineral build-up will limit proper seating for closing.
Your LP igniting issues are related to the part of the heater that uses LP and is in the ignition sequence---orifice on gas tube, cleanliness of air tube, condition of ignitor, etc. You may also have a failed gas valve but that should be the last in a chain of diagnosis. Clean everything up in the LP firing area and see if you have success. There are a few threads on this Forum that deal with water heater repair and service manuals are available here:
Bryant Service