In addition to former post, that is the conclusion everytime this question pups up, but never prooved , so I did a test once.
Measured the pressure of cartire with about 1000 lbs on it,on a cold day on the ground , so ambiƫnt temp while test was the same, also inside tire temp because not driven yet.
Did 3 measurements , then yacked up the tire from the ground, so zero load on it, and measured 3 times again , then on the ground 3 times, off the ground 3 times and again on the ground 3 times.
During the test the pressure dropped a little because every time I pressed the cheap digital device agaist the valve , a little air escaped.
At the end the presssure on the ground was 1/2 psi lower then in the beginning on the ground. and measured pressure within some deveation the same.
so this prooves the argument that when more load on tire , the pressure stays the same .
You can take the spare to the punp and fill it to fi 65 psi , then mount it on the car and yack down the car so full load on tire, and pressure stays 65 psi.