Triple DITTO.
Check and set them at the ambient temp. in the morning before you leave when they've been in shade for at least a few hours. Unless you've been to a scale and have looked up a chart for loading vs. pressure, run them at the sidewall max. psi. If you are significantly changing altitude and outdoor temps. on a leg of a trip, you may need to reduce psi or add some air the next morning. Some will disagree, but if you are on a long trip (in days), it's a good idea to check the pressure on each leg of the trip to see if you have a slow leak in a tire.
If you have ST tires, it's very important to stay below 65 mph, never ever tow on under-inflated tires and make sure the tires aren't overloaded otherwise you can end up with a blowout. Overloading can be from inadequately sized tires by the RV manufacturer, being heavier on one side due to a slide and/or by having one or more full holding tanks. One of the best things you can do is weight your TT and TV at a scale so you know the actual tongue wt. and actual total wt. of the trailer.
A good digital pressure gauge is a good tool to have and a TPMS is also a good idea if you plan to travel around much.