Ok there is a point of diminishing returns but the general rule is the bigger the wire the lower the loss.
However.. if you are only drawing say 20 amps.. 2/0 (not 20 but 2/0) is overkill
if you are drawing 200 amps 2/0 is the smallest I'd recommend.
For battery to battery at least the same size as battery to RV.
Home was where I park it. but alas the.
2005 Damon Intruder 377 Alas declared a total loss
after a semi "nicked" it. Still have the radios
Kenwood TS-2000, ICOM ID-5100, ID-51A+2, ID-880 REF030C most times