With a diesel, there are two times you want/need an additive:
If storing the fuel over 2 months in the summer or 3 months in the winter, add a BIOCIDE to keep algae from growing. Biobar JF is a common one.
If you fill up in summer or fall and will be keeping the fuel into winter (with below freezing conditions) add an anti-gel. PS brand is stocked in most Walmarts. If filling in winter, the fuel already has been formulated so it will not gel.
Also, be sure to store your diesel tank FULL to minimize condensation.
Others can probably advise on "care and feeding" of your DEF.