Because it doesn't work and will fail.
For whatever reason, silicone caulking randomly will not get good adhesion to both surfaces and no way to predict exactly where it doesn't get good adhesion, creating random weak spots. Those random weak spots over time fail just enough to allow water to wick it's way right past the silicone.
Additionally, cured silicone is a real bear to remove and once cured not even new uncured silicone will adhere to the old cured silicone, ever, making your next repair a real time consuming nightmare to correct.
Silicone caulking is pretty much worthless.
Lets just stick with what does work, remove the window/door frames, remove the old butyl rubber caulking (removes easily with mineral spirits) and refresh with new butyl rubber caulking (rope or flat).
Yes, butyl caulking does dry out over time.
Yes, butyl caulking does crack over time.
Yes, butyl caulking will need replaced periodically.
But, even with those issues it simply works and will do so for 5-6 yrs at a time and unlike silicones it is easily replaced and if you compared the cost of butyl caulk vs a bunch of tubes of silicone it is very low cost.
And don't be tempted to take the lazy way out and slather on any caulking on the outside of the frames or trim, it just wastes money, time and looks horrible and will leak even faster.