I would say no. A stock Ram 3500 will have load E rated tires, so that is what your stock monitor is set for. A load E rated tire will be rated up to 80 psi. (at least on my Dodge/Ram with Cummins, the truck's sticker was 60 psi on the front, 70 psi on the rear. , I haven't double checked inflation charts recently but I believe 80 psi is the low end and 110 psi is the high end for 19.5's.
I've got 19.5's but don't have TPMS monitoring so this is just an opinion.
2005 Dodge Ram 2500 CTD,4X4,NV5600
2014 Adventurer 86FB