Not only will running the max pressure on the sidewall make the RV ride like a brick, it can also have a huge detrimental effect on handling. There's a reason the the text reads "maximum" rather than "correct" or "recommended", just as there is a reason that manufacturers publish inflation/weight tables.
I drove my Class C for 15 years as a white knuckle, E-ticket ride; it was not fun at highway speeds, and I had to have 2 hands on the wheel and be paying constant attention with constant corrections. Alignments, shocks, sway bars made very little improvement. I was running all 6 tires at 70lbs, which was actually 10 lbs below the max listed on the sidewall. Then, for "grins & giggles", I had the rig weighed, and based on the axle weights, I was overinflated. I dropped the rears to 60lbs, and dropped the fronts to 45lbs, both according to the charts, and the difference in handling was immediate and dramatic. The coach drove like a whole new rig, and I could actually relax, drive with one hand, AND even eat fast food while driving! My only regret is that I waited 15 years to do it, thinking like many here suggest, that the max pressure (or close) was the safest and the best way to go. Wrong.
My new (to me) class A, with new tires installed by the dealer, is running 90psi all the way around, although the sticker in the door recommends 90psi front / 80psi rear. It is slightly squirrely at freeway speeds. I am, without a doubt, going to weigh it and adjust tire pressures accordingly.
BTW, back to the OP's initial question; I too take quick temp gun readings on my tires at stops, as an added way to catch a problem before it gets worse. They generally run about 120-130 degrees (summer, desert driving), slightly hotter on the inner duals than the outer, and slightly hotter on the left side than the right.