There's really no need for a schematic of the two electrical systems. They are all connected generically with user safety and usability in mind. Unless you need to replace wiring, a schematic won't help you one bit.
Here's a good site to understand the 12V system:
12 volt side of lifeHere's another site with more advanced electrical explanation:
RV electrical and solarAs was mentioned, put a meter across the battery terminals after starting the vehicle. Voltage should be above 13V. That is how you test an alternator for function. BTW, alternators don't have a last gasp. They have a major stroke and die instantaneously.;)
Good luck with the electrical. I think you should maybe get away from your lead mechanic. He may be a "parts changer" instead of having diagnostic skills.