Most 5th wheels are designed to have about 20-25% of the GVW on the king pin. It is important to check what the manufacturer says. Many people don't properly load their trailer, nor even look to see what the cargo capacity is. Sometimes the cargo capacity on an RV is so low that you can't carry water, let alone anything else. Many 5th wheels have around 1500 pounds of cargo capacity, which is insanely low. My 5th wheel is rated for almost 3300 pounds of cargo. Many people do not realize just how much clothing and food weigh, let alone everything else thrown into a trailer. Some people add cargo or bike racks on the rear of their trailer. These racks can weigh 100 pounds empty.
The OP didn't state if the 14000 pounds was GVWR or empty weight. If we assume it is GVWR then the king pin should have between 2800 and 3500 pounds. If it is 14000 pounds curb weight, empty, then he's truly over loaded. He didn't even say which 5th wheel, so we are left guessing.
Some 2500's lightly configured may have a 2800 pound cargo capacity. But that doesn't include the 5th wheel hitch (about 250 pounds or 40 pounds for an Anderson hitch), tools, passengers, drinks, snacks, (upgrades to tires, wheels, suspension) etc. I doubt that you can find a 2500 with 3200++ pounds of cargo capacity.
RAM 2500's are "derated" to 10000 pounds of GVWR for cost savings. Good luck getting over 3000 pounds of cargo capacity from a RAM. I looked at the cost difference between a 2500 and 3500 and chose a 3500 SRW.
Will the RAM 2500 pull the 5th wheel. Yes, just not legally or, IMHO safely. The spring shocks on the 2500 are for better ride comfort compared to heavy leaf springs. Many many people report that their 2500's rear sways while pulling near max load 5th wheels. I've talked to many people who have traded up because of how bad the sway is when it's windy and/or going through mountains or along winding roads near rivers/creeks.
Once you get to this size 5th wheel, you really want a long wheel base. For RAM this means a Crew Cab with 8 foot bed or the Mega Cab with short bed. The long wheel base increases stability, people forget that they are pulling a trailer that may be 25-35 foot behind their truck. You want the truck in charge, not the trailer. Such a truck is about 22 foot long, with a wheel base around 14 foot long.
What is truly scary is that people buy oversized 5th wheels for their 2500's, when often they are close to needing a DRW (I've seen people towing 40 foot toy haulers with 2500's). These tend to be the same people driving 70, 75, 80 mph or even faster down the freeway. I've seen people pass me while I'm going 85 mph (in Montana) while towing a large 5th wheel (and sometimes a 2nd trailer). A heavy truck and 5th wheel might take twice as long to stop at 70 mph as 60 mph, at 80+ mph it takes many football fields to stop.
RV's will have blowouts, it's not a matter of if, just when. I can't imagine going at those speeds while a tire blows.
Personally, I limit myself to 63 mph max, unless needing to go a few mph faster to pass. I don't doubt for a minute that my 2019 RAM 3500 SRW Crew Cab Long bed with HO engine can pull my 35 foot 5th wheel at 100 mph going over a mountain pass. It is a towing beast. Curves, potholes, rocks in the road, crazy drivers pulling in front of you and then slowing down, or pulling onto the freeway at 45 mph, sudden stops because of accidents, road construction, a police car on the side of the freeway or grandma going 40 mph on the freeway will always be a thing.