The OP was about setting a scale, which involves the safety of propane. Essentially, then, it is a procedure to make sure that a given cylinder is not overfilled (a dangerous condition). It is simple mathematics: the weight of the propane plus anything else that presses down on the scale (the cylinder itself, the hoses and valves -- 6 pounds in our set-up).
Charging for propane is completely separate and certainly does not involve considerations of safety. I suppose there are places that charge by the pound, though i haven't run across any personally. Most places will charge by the gallon (as i do) or will simply have a flat charge (which can be a bit of a rip off, imho).
Note, then, that if we were effectively to underfill a cylinder, then it would also merely involve fewer gallons of propane and, as a result, less money on the sale.
Lynn