You MUST get a Voltage reading at the Chassis Batteries when they are boiling. You seem to have a 1999 Thor product. Even if you have a BI DIRECTIONAL charge system, That will NOT cause the Chassis Batteries to boil. If so, then the Coach would boil. Also, The fact that the chassis are boiling almost immediately when you hooked them up points to a connection problem. Rarely will batteries boil that quick, UNLESS, they are defective batteries to begin with. Now, IF you have an Inverter/Charger which will have a HIGH BULK rate charge when first connected to 120 voltage, AND you somehow hooked the Inverter/Charger POS cable TO THE CHASSIS BATTERIES, that may cause them to boil. Chassis batteries are NOT meant to have a high bulk charge and will overheat and boil from a bulk charge. A simple test would be to disconnect the Chassis batteries and then check if your Inverter is powered if you have an Inverter. IF it is NOT powered, then you connected the Inverter to your chassis batteries.
AS the other poster stated, when you replace batteries and then you get a failure. 99 percent of the time it is you failed to connect correctly. I speak from 40 years experience. I have had customers swear they did not connect wrong and when they bring the unit in, I find the problem in less than 5 minutes, They did connect wrong or missed a cable or 2. Doug