Your owner's manual pressures are normally based on both the capacity of the axles and the original tire capacity, or in other words, as if you loaded to the maximum capacity of the coach (GVWR). The higher rated new tires will give a bit of a harder ride as the side walls are stiffer due to the increase capacity.
Without knowing your actual weights on the axles, or better still each wheel position, you're into unknown territory changing pressures especially reducing the pressure. Drop the pressure too much and you risk potential tire damage and worse yet a blow out. Get the coach weight checked with a full load (including passengers) that you normally take on a trip then cross reference the tire manufacture's chart for the recommended pressure for optimum tire performance and ride comfort. I don't think the ride will improve as much as you may like but it's worth a try.
2006 Hurricane 31D built on a 2006 Ford F53