Harvey51 wrote:
I thought the advantage with nitogren was for psi stability. Hot or cold it's the same. Am I right?
All gases follow the universal gas law PV= RT so nitrogen filled tires respond exactly the same way to temperature changes. There is a temperature/pressure affect when there is liquid water condensed in the tire and then it heats up and goes gaseous - this doesn't happen with nitrogen because water is removed completely in the process of seperating it from air by liquification.
Some say oxygen can find its way through the rubber slightly more easily so pressure may drop less over winter with nitrogen. If true, this also implies that oxygen will pass from the air outside into the tire with no oxygen so your nitrogen filled wheels may actually slightly increase in pressure over time.
More info here: http://www.tirerack.com/tires/tiretech/techpage.jsp?techid=191
It called the "ideal gas law" because it only really estimates what might happen. While I can imagine a molecule or two of O2 from the air gettng into a tire, the oxygen (and air) will move towards a state of greater entropy. Maybe you are thinking of the gas constant? Under the ideal gas law, gasses of a different mole weight will behave differently. The law also does not consider things like leakage rates, moisture content, and the reactivity of the elements and compounds involved. Crunch the math on gasses at the proposed pressures and temps and you find it makes no difference anyway.
Pv=nrt often get brought into the N2 conversation, but it all it really shows is that all gasses are good at filling tires. Its the phase change of Condensable materials that can alter the pressures more radically. In other terms, things in there that turn to liquid or solids under reasonable temperatures are a bigger problem. H2O is one material that comes to mind.