Hi Hunter_rv,
There are DC to DC converters that are efficient.
For the starter battery maintenance, look at a Trik-L-Start
I'd go for a 48 volt battery bank.
For my detailed thoughts on solar, surf here:
https://freecampsites.net/adding-solar/
Regards, Don
My ride is a 28 foot Class C, 256 watts solar, 556 amp-hours of Telcom jars, 3000 watt Magnum hybrid inverter, Sola Basic Autoformer, Microair Easy Start.