I decided to test how easily the caulk would come out. It comes out pretty well, so I removed the driver's side caulk in about an hour.
I blunted the tip of a new blade in my utility knife, and drew it along the molding side of the caulk, being careful not to go to the bottom or hit the roofing. At first I only did an inch or two at a time to make sure of how deep I was running the knife. But after a while I was taking two foot runs.
Just one cut along the molding, then pull up the end and it comes right out. There were thin remnants but they practically wipe off by either back-dragging the knife blade over them, or using another blade type tool like a putty knife. I dampened a rag with WD40 to wipe it down. It's not good for roofs but then nothing is. I made sure to wipe it off right away.
There is putty tape under the molding and it appears to be in fine condition. I don't think the awning side will be as fine, because there is already one gap visible before I start. So I could have ignored the driver side, possibly. But I have had an RV that needed structural repairs due to leaks, so I'm pretty finicky about caulking.
I thought I had seen the non-sag Dicor on the shelves of my area RV dealers, but I called them and came up empty. One of them suggested silicone, and one suggested another sealant that doesn't stick to TPO (when I looked it up). Dealers, jeesh. So I have to order the caulk. Good thing the putty tape is in good shape.
Bottom line, it's worth checking to see if you have any suspect areas. Beyond that, your mileage may vary.
Currently RV-less but not done yet.